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81.
82.
Remeasurements of weathering rates at six sites on the base of the balustrade of St. Paul's Cathedral gave substantially lower mean results (0.06 mm a?1, 1980–1985) than for earlier results (0.14 mm a?1, 1980–1981). Statistical analysis of the data showed that for five of the sites there were no significant differences between the measurement periods. The only significant spatial difference was for the southwest (exposed) site which was greater than the other sites for 1980–1981, but not at later times. This site also showed the only significant decrease over time. If this site is included in the statistical analysis, the whole set shows a significant decrease over time; omitting this site from the data removes any significant differences over time. The results for this one site for 1980–1981 thus have significant bias on the data body as a whole. Methodological problems, such as rock erosion by the probe and temperature effects, are thought to have minimal effect on the interpretation of the data. Calibrations showed that measurements were accurate to ±0.006 mm and that only results of a change ≥ 0.02 mm were reliably interpretable as different. Remeasurements of the Lead Plug Index (LPI) for the top of the balustrade in 1987 gave a mean rate for 1718–1985 of 0.081 mm a?1. This is not significantly different from the 1718–1980 mean rate of 0.078 mm a?1 but the data are not directly comparable, the 1987 sample being smaller than the 1980 set. For the 1987 data, the only statistically significant differences are for the southeast rate ≧ northeast and for a rise in rate in the northeast quadrant. The LPI data are comparable to most of the 1980–1985 MEM data. The conclusion is that most erosion rates have neither increased nor decreased significantly in the measurement time, except for a significant decrease at one (southwest) site from 1980–1981 to 1981–1982. Such a sustained level of erosion gives cause for concern in the context of stone conservation. Causative factors of air quality are discussed and while SO2 levels have decreased, NO2 and smoke levels show increases. An overall decrease in stone decay in association with the decrease in SO2 levels is thus not in evidence.  相似文献   
83.
Palaeolimnological studies at Llangorse Lake, Wales, constitute part of the British contribution to IGCP Project 158 (The Palaeohydrology of the Temperate Zone in the Last 15000 Years). The lake has been adopted as the Reference Site for the South Wales region under Subproject 158B (Lake and Mire Environments) and is located in the Reference Area for Britain: the Severn Basin. Results of biological, physical, and multielement chemical analyses on a 12.35 m Livingstone core are presented and compared with previous analyses on short Mackereth cores taken from two troughs in the lake basin. Human impact upon post-glacial sedimentation is assessed with reference to sediment chemistry, physical properties, and sedimentation rates, based on relative pollen, 14C, and 210Pb dating. Vegetational history of the catchment is inferred from a pollen diagram for a section of the core from c. 8 to 6.75 m depth in which evidence for human impact is first apparent. Water content, loss on ignition, and carbonate content are presented for the whole core; density, water content, loss on ignition, carbonates, and elemental analyses of P, Ca, Mg, K, Ti, Al, Fe, and Mn for the interval 6 75 and 8.25 m depth. Sedimentation rates were low during Boreal and Atlantic times (c. 9000- 5000 BP), rose significantly from the time of the elm decline (estimated at 5000 BP) and increased further at c. 1800 BP when nekron muds were succeeded by deposition of silty clay. Inferred rates of erosion of soils from the catchment are discussed and related to sediment chemistry.  相似文献   
84.
Intensive water sampling in conjunction with hydrological observations was conducted during three different rainstorms in order to understand the effects of rainfall events on the temporal variation of streamwater chemistry in a small headwater forest catchment. Concentrations of Na+ and SO42? decreased as the discharge rate increased. Hydrograph separation of the components was made using the three‐component model based on the end‐members mixing analysis (EMMA). The three end‐members were:
  • 1 the groundwater in the saturated zone that prescribes the chemistry of the baseflow;
  • 2 the throughfall that dilutes the streamwater;
  • 3 the groundwater in the transient saturated zone prescribed, which was dependent on the groundwater level.
When the groundwater level was lower, only the two components, groundwater in the saturated zone and throughfall, affected the streamwater chemistry. When the groundwater level rose and the saturated zone spread, the groundwater in the transient saturated zone became the third component. When the groundwater in the transient saturated zone contributed to the discharge, this component became the dominant source and the streamwater chemistry was affected by the groundwater chemistry in the transient saturated zone. When this component was discharged as the saturation overland flow, the streamwater chemistry was greatly affected by this component. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   
85.
李荣容  包为民 《水文》2007,27(6):25-27,21
遥测系统观测的雨量资料常会包含粗差,根据降雨量的特征,结合抗差理论,包为民等曾提出三步抗差修正方法。将此法应用到龙颈上水库等10个水库流域的实测资料当中,验证其有效性,并分析比较各步抗差修正的效果及降雨特征与抗差效果之间的关系。结果表明,抗差修正方法可行,且第一步和第三步结合的修正效果最好;降雨中心较明确,多年降雨特征相似,强度变幅稳定的洪水,不容易出现误抗。  相似文献   
86.
87.
Intra‐urban cooling rates were monitored for a year in the centre of Göteborg on the Swedish west coast. Five sites with different building geometry ‐ from dense canyon to open space ‐ within a radius of 300 m were analysed. Results showed two modes of cooling during the night. In the first mode, the cooling was site‐dependent ‐the open space cooled the most and the dense canyon the least. In the second mode, which began about 3–4 hours after sunset, all sites cooled at the same rate. Our hypothesis is that in the early part of the evening both radiative divergence and sensible heat dominate the cooling. However, as the evening progresses, a spatially homogeneous inversion is established which controls the radiative cooling, making the cooling independent of both surface geometry and surface type. From April to November the sites cooled rapidly around sunset and the cooling slowly decreased during the rest of the night. However, between December and March, the cooling was less intense, with an almost constant rate during the entire night. It has been suggested that this might be the result of the draining of stored solar heat during the summer and a continuous flux of anthropogenic heating during the winter.  相似文献   
88.
The Chilean lake district includes diverse lentic ecosystems along ca. 700 km of the country (36°–43°S), including the “Nahuelbutan lakes”, “Araucanian lakes” and “Chiloe lakes”. This area is recognized as an important “hot spot” of benthic freshwater biodiversity in Southern South America. In Chilean temperate lakes, increased nutrient loads of P and N caused eutrophication, particularly in the Nahuelbutan Lakes. The freshwater Hyriidae mussel Diplodon chilensis (Gray, 1828) which is one of the most abundant species in Chilean temperate lakes, is known to be very susceptible to eutrophication. This species presents a clear reduction in its geographic ranges and is considered to be a threatened species in many Chilean lakes. In this study, we used a correlative approach to determine how eutrophication-driven changes in the food supply and in geographical parameters of different Chilean lakes affected the shell growth rates of D. chilensis. The results obtained from sclerochronological analyses of the mussel shells suggest an association with a group of environmental variables, including geographical types (negative), such as latitude and altitude, and limnological types (positive), especially phosphorous and turbidity. However, the D. chilensis populations under extreme conditions of turbidity in eutrophic and hypertrophic lakes are extinct or nearly so. The high positive correlation of the mean D. chilensis growth rates with orthophosphate (R=0.76; P<0.05), in relation to dissolved inorganic nitrogen, suggests that P is the major limiting factor of the primary productivity in Chilean temperate lakes. We discuss some implications of our results in terms of the conservation of biodiversity in temperate lake ecosystems at different taxonomic levels.  相似文献   
89.
The secondary mineral budget on Earth is dominated by clay minerals, Al-hydroxides, and Fe-oxides, which are formed under the moderate pH, high water-to-rock ratio conditions typical of Earth's near-surface environment. In contrast, geochemical analyses of rocks and soils from landed missions to Mars indicate that secondary mineralogy is dominated by Mg (± Fe, Ca)-sulfates and Fe-oxides. This discrepancy can be explained as resulting from differences in the chemical weathering environment of Earth and Mars. We suggest that chemical weathering processes on Mars are dominated by: (1) a low-pH, sulfuric acid-rich environment in which the stoichiometric dissolution of labile mineral phases such as olivine and apatite (± Fe–Ti oxides) is promoted; and (2) relatively low water-to-rock ratio, such that other silicate phases with slower dissolution rates (e.g., plagioclase, pyroxene) do not contribute substantially to the secondary mineral budget at the Martian surface. Under these conditions, Al-mobilization is limited, and the formation of significant Al-bearing secondary phases (e.g., clays, Al-hydroxides, Al-sulfates) is inhibited. The antiquity of rock samples analyzed in-situ on Mars suggest that water-limited acidic weathering conditions have more than likely been the defining characteristic of the Martian aqueous environment for billions of years.  相似文献   
90.
We present observations of electric and magnetic field variations from proton (about few Hz) to electron cyclotron frequencies (about few kHz) obtained by STAFF instrument on Cluster satellites during two cusp crossings, at ∼6 R E altitude, in September 2002. The cusp was identified by the presence of intensive fluxes of counter streaming electrons with low energies and broadband wave activity which is typical for this region. Special attention is given for the interval of measurements when the waveform of the magnetic field fluctuations was taken in this region by CLUSTER satellites. The wave has been processed using the wavelet and bispectral analysis. Results showing the cascade of turbulence and wave-wave interactions are presented in this paper. A three wave process can be responsible for the broadening of the wave spectra in the polar cusp.  相似文献   
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